2 Crystal structuresĬrystallographic studies have established that the clay minerals are composed of sheets of tetrahedral silicon dioxide (SiO 2) and octahedral aluminium oxide (Al 2O 3) linked through bridging oxygen atoms. As a result, clay is a major component of soil all over the world, with a variety of properties according to the precise conditions that applied during its formation. They are also separated by size according to what settles out first. When transported by water the particles continue to be ground finer and finer by the action of other rocks. The clay is either found where it had been formed or it can be carried by rivers and deposited elsewhere. K 2O.Al 2O 3♶SiO 2 + 2H 2O → Al 2O 3.2SiO 2.2H 2O + K 2O(SiO 2) + 3SiO 2įeldspar a clay mineral in solution in the clay Although these rocks seem solid and eternal, over millions of years the effect of rain, made slightly acidic by dissolved CO 2, does dissolve some of the alkali and alkaline earth metal oxides leaving the silicon and aluminium oxides: Over the geological timescale a great deal of feldspar has been eroded through a weathering process, mainly through the action of water. A typical example is orthoclase, whose approximate composition is given as K 2O.Al 2O 3.6SiO 2. They are aluminium silicates, also incorporating alkali and/or alkaline earth metals. The feldspar group of minerals comprise around 60% of the earth's crust. If at this point the clay object is put into water it will disintegrate and can be returned into a workable state. The kaolinite hydroxyls become hydrogen bonded to the next layer, forming a stronger, firmer structure ('green ware'). In other words, clay can be moulded into a shape, which it then keeps.Īs the clay dries, water molecules escape from between the clay sheets, so these move closer together (the clay shrinks by 5% or more). They are weak enough to allow the clay sheets to slide past each other when some force is applied, but strong enough to keep them in position once the force is removed. These are weak but still significant forces. This property is readily understood if we consider that the layers are separated by a thin layer of water molecules which are linked to neighbouring layers via hydrogen bonds. The essence of the plasticity is that the clay takes the shape given to it by applying a force and it keeps that shape unless some other force acts on it. In all methods it is essential for the clay to contain some water not too much, because that makes the clay too soft and unworkable, or even turns it into 'slip' - a dispersion of clay in water. The potter's wheel was invented about 7000 years ago and has become the method of choice for many potters. Hand building is the earliest method and is still widely used. Although much is now known about the materials and their structures, there are so many variables and the structures so complex, that the empirical approach still largely dominates pot making. More recently, with the development of modern analytical techniques, the elucidation of their structures has been possible. A scientific approach to the process only became possible in the past two centuries, initially in establishing the compositions of the materials used. The immense strides in the making of pots were the result of patient trial and error by thousands of potters over thousands of years. Subsequently the Chinese steadily improved kilns and so it was possible to produce more and more highly decorated stoneware and porcelain. About 7000 years ago the Egyptians discovered the art of glazing their pots. 1 Since then, the craft of pottery has developed in all parts of the world, both for the practical purposes of making usable vessels for food and storage, and as expressions of the instinct for art and ritual. The earliest known example of a pottery vessel was made around 18 000 years ago. A small figurine of a woman is the earliest known object made of fired earth, dated to almost 30 000 years ago. Making things from burnt clay has been part of human experience for many thousands of years. Source: © VICTORIA AND ALBERT MUSEUM, LONDON/SALTING BEQUEST
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